Polymerization of acetylene: polyynes, but not carbyne-Reference-Cited by-同舟云学术

Polymerization of acetylene: polyynes, but not carbyne

Published:2017 Issue:5 Volume:4 Page:668-674
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Prenzel Dominik¹²³,Kirschbaum Rolf W.⁴⁵³,Chalifoux Wesley A.⁶⁷⁸⁹^ORCID,McDonald Robert⁶¹⁰¹¹¹²,Ferguson Michael J.⁶¹⁰¹¹¹²,Drewello Thomas⁴⁵³,Tykwinski Rik R.¹²³⁶¹⁰^ORCID

Affiliation:

1. Department of Chemistry and Pharmacy & Interdisciplinary Center for Molecular Materials (ICMM) University of Erlangen-Nuremberg (FAU)

2. 91054 Erlangen

3. Germany

4. Department of Chemistry and Pharmacy & Interdisclipinary Center for Molecular Materials (ICMM) University of Erlangen-Nuremberg (FAU)

5. 91058 Erlangen

6. Department of Chemistry

7. University of Nevada

8. Reno

9. USA

10. University of Alberta

11. Edmonton

12. Canada

Abstract

Polymerization of acetylene in the presence of sterically-hindered endgroups leads to polyynes, but with lengths shorter than by stepwise syntheses.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/QO/C6QO00648E

Reference51 articles.

1. The era of carbon allotropes

2. Synthesis of polyynes to model the sp-carbon allotrope carbyne

3. Synthetic Strategies for Oligoynes

4. Y. Tobe and T.Wakabayashi, in Acetylene Chemistry, ed. F. Diederich, P. J. Stang and R. R. Tykwinski, Wiley-VCH, Weinheim, 2005, ch. 9

5. Synthesis of extended polyynes: Toward carbyne

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