Armed by Asp? C-terminal carboxylate in a Dap-branched peptide and consequences in the binding of CuII and electrocatalytic water oxidation

Author:

Szyrwiel Łukasz1234,Lukács Dávid567,Srankó Dávid F.567,Kerner Zsolt567,Kotynia Aleksandra89104,Brasuń Justyna89104,Setner Bartosz1112134,Szewczuk Zbigniew1112134,Malec Katarzyna1234,Pap József S.567ORCID

Affiliation:

1. Dept. of Chemistry of Drugs

2. Wrocław Medical Univ.

3. 50-552 Wrocław

4. Poland

5. Surface Chemistry and Catalysis Dept.

6. MTA Centre for Energy Research

7. Hungary

8. Dept. of Inorganic Chemistry

9. Wrocław Medical University

10. 50-552 Wroclaw

11. Faculty of Chemistry

12. Univ. of Wrocław

13. 50-383 Wrocław

Abstract

C-Terminal carboxylate in branched peptide allows insight into water oxidation electrocatalysis by Cu-complexes, revealing differences to homologues with varied modules.

Funder

Magyar Tudományos Akadémia

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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