Electrophilic terminal arsinidene-iron(0) complexes with a two-coordinated arsenic atom-Reference-Cited by-同舟云学术

Electrophilic terminal arsinidene-iron(0) complexes with a two-coordinated arsenic atom

Published:2019 Issue:97 Volume:55 Page:14669-14672
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Sharma Mahendra K.¹²³⁴⁵^ORCID,Neumann Beate¹²³⁴⁵,Stammler Hans-Georg¹²³⁴⁵,Andrada Diego M.⁶⁷⁸⁹,Ghadwal Rajendra S.¹²³⁴⁵^ORCID

Affiliation:

1. Anorganische Molekülchemie und Katalyse

2. Lehrstuhl für Anorganische Chemie und Strukturchemie

3. Centrum für Molekulare Materialien

4. Fakultät für Chemie

5. Universität Bielefeld

6. Allgemeine und Anorganische Chemie

7. Universität des Saarlandes

8. D-66123 Saarbrücken

9. Germany

Abstract

The electrophilic arsinidene complexes 5 and 6 featuring a two-coordinated arsenic atom have been isolated as crystalline solids. Complex 5 readily reacts with an NHC nucleophile (IMe₄) to give the Lewis adduct 7.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C9CC08630G

Reference60 articles.

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4. Phospha‐ and Arsaalkenes RE=C(NMe 2 ) 2 (E = P, As) as Novel Phosphinidene‐ and Arsinidene‐Transfer Reagents

5. Phosphinidenes

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