Cooperative benzylic–oxyallylic stabilized cations: regioselective construction of α-quaternary centers in ketone-derived compounds-Reference-Cited by-同舟云学术

Cooperative benzylic–oxyallylic stabilized cations: regioselective construction of α-quaternary centers in ketone-derived compounds

Published:2015 Issue:11 Volume:6 Page:6312-6319
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Dange Nitin S.¹²³⁴,Stepherson Jacob R.¹²³⁴,Ayala Caitlan E.¹²³⁴,Fronczek Frank R.¹²³⁴,Kartika Rendy¹²³⁴

Affiliation:

1. Department of Chemistry

2. Louisiana State University

3. Baton Rouge

4. USA

Abstract

Herein we describe a direct capture of benzylic–oxyallylic stabilized carbocations with high value nucleophiles towards regioselective construction of α-quaternary centers.

Funder

National Science Foundation

Louisiana State University

Louisiana Board of Regents

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC01914A

Reference66 articles.

1. The Nazarov cyclization in organic synthesis. Recent advances

2. Interrupting the Nazarov reaction: domino and cascade processes utilizing cyclopentenyl cations

3. Asymmetric Nazarov cyclizations

4. Catalytic Nazarov Cyclization: The State of the Art

Cited by 27 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Brønsted‐Acid Mediated Synthesis of Symmetrical and Unsymmetrical Indolo[2,3‐a]carbazoles from Indoles and α‐Functionalized Ketones;Advanced Synthesis & Catalysis;2023-11-14

2. Copper(I)-Catalyzed Synthesis of Unsymmetrical All-Carbon Bis-Quaternary Centers at the Opposing α-Carbons of Cyclohexanones;Organic Letters;2022-06-29

3. Lewis Acid-catalyzed Decarboxylative Cyanation of Cyclic Enol Carbonates — Access to Multi-substituted β-Ketonitriles —;Chemistry Letters;2022-04-05

4. Brønsted Acid-Catalyzed Intramolecular α-Arylation of Ketones with Phenolic Nucleophiles via Oxy-Allyl Cation Intermediates;European Journal of Organic Chemistry;2020-03-13

5. Transition metal-free synthesis of α-aryl ketones via oxyallyl cation capture with arylboronic acids;Organic Chemistry Frontiers;2020