Glycerol oxidehydration to pyruvaldehyde over silver-based catalysts for improved lactic acid production

Author:

Lari G. M.12345,García-Muelas R.678910,Mondelli C.12345,López N.678910,Pérez-Ramírez J.12345

Affiliation:

1. Institute for Chemical and Bioengineering

2. Department of Chemistry and Applied Biosciences

3. ETH Zurich

4. CH-8093 Zurich

5. Switzerland

6. Institute of Chemical Research of Catalonia

7. ICIQ

8. The Barcelona Institute of Science and Technology

9. ES-43007 Tarragona

10. Spain

Abstract

Supported silver nanoparticles are identified as the optimal catalyst to convert glycerol into pyruvaldehyde. The use of this intermediate instead of dihydroxyacetone enables an alternative greener process for the preparation of lactic acid.

Funder

Secretaría de Estado de Investigación, Desarrollo e Innovación

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Reference44 articles.

1. T. Werpy and G. R.Petersen, Top Value Added Chemicals from Biomass: Vol. I - Results of Screening for Potential Candidates from Sugars and Synthesis Gas, US DOE, 2004

2. Technology development for the production of biobased products from biorefinery carbohydrates—the US Department of Energy’s “Top 10” revisited

3. Polylactic Acid Technology

4. Catalytic transformations of biomass-derived acids into advanced biofuels

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