BODIPY catalyzed amide synthesis promoted by BHT and air under visible light
Author:
Affiliation:
1. Key Laboratory of Applied Surface and Colloid Chemistry
2. Ministry of Education
3. School of Chemistry and Chemical Engineering
4. Shaanxi Normal University
5. Xi'an
Abstract
A novel and efficient protocol for the synthesis of amides is reported via a BODIPY catalyzed oxidative amidation of aromatic aldehydes under visible light, with broad substrate scope and mild reaction conditions. Mechanistic studies reveal that dioxygen could be activated through both an ET and SET pathway to form the active peroxide intermediates.
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/OB/C6OB00736H
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