BiTEMPS methacrylate dynamic covalent cross-linker providing rapid reprocessability and extrudability of covalent adaptable networks: high-yield synthesis with strong selectivity for disulfide linkages-Reference-Cited by-同舟云学术

BiTEMPS methacrylate dynamic covalent cross-linker providing rapid reprocessability and extrudability of covalent adaptable networks: high-yield synthesis with strong selectivity for disulfide linkages

Published:2024 Issue:21 Volume:15 Page:2167-2176
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Debsharma Tapas¹^ORCID,Purwanto Nathan S.²^ORCID,Fenimore Logan M.¹^ORCID,Mitchell Sarah³^ORCID,Kennedy Jayme³^ORCID,Torkelson John M.¹²^ORCID

Affiliation:

1. Department of Chemical and Biological Engineering, Northwestern University, Evanston, IL 60208, USA

2. Department of Materials Science and Engineering, Northwestern University, Evanston, IL 60208, USA

3. Braskem America, 550 Technology Drive, Pittsburgh, Pennsylvania 15219, USA

Abstract

A dialkylamino disulfide-based dynamic covalent cross-linker (BTMA) was synthesized with high purity and selectivity for disulfides and was used to produce rapidly reprocessable and extrudable covalent adaptable networks with n-hexyl methacrylate.

Funder

Northwestern University

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/PY/D4PY00160E

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