Cobalt-catalysed transfer hydrogenation of quinolines and related heterocycles using formic acid under mild conditions

Author:

Cabrero-Antonino Jose R.123,Adam Rosa123,Junge Kathrin123,Jackstell Ralf123,Beller Matthias123ORCID

Affiliation:

1. Leibniz-Institut für Katalyse e.V. an der Universität Rostock

2. 18059 Rostock

3. Germany

Abstract

For the first time, transfer hydrogenation of quinolines and related heterocycles is performed with a non-noble metal based catalyst. [Co(BF4)2·6H2O] in combination with phosphine L1 catalyses selectively, the mild reduction of N-heteroarenes using formic acid as hydrogen donor.

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Reference62 articles.

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4. Chemistry and Biology of the Tetrahydroisoquinoline Antitumor Antibiotics

5. Advances in the Chemistry of Tetrahydroquinolines

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