Heterobimetallic catechol-phosphine complexes with palladium and a group-13 element: structural flexibility and dynamics-Reference-Cited by-同舟云学术

Heterobimetallic catechol-phosphine complexes with palladium and a group-13 element: structural flexibility and dynamics

Published:2014 Issue:23 Volume:43 Page:8911-8920
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Bauer G.¹²³,Nieger M.⁴⁵⁶,Gudat D.¹²³

Affiliation:

1. Institut für Anorganische Chemie

2. University of Stuttgart

3. 70550 Stuttgart, Germany

4. Laboratory of Inorganic and Analytical Chemistry

5. University of Helsinki

6. FIN-00014 Helsinki, Finland

Abstract

Condensation of a catechol phosphine Pd complex [Pd(catphosH)₂] with group-13 element acetylacetonates yields complexes [M(L)_n(catphos)₂Pd] or [M{(catphos)₂Pd}₂]H (M = Al, Ga, In) whose relative stability is controlled by the size of the group-13 element. ¹H NMR studies give insight into the proton mobility in a Pd₂In complex.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT00785A

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