Nonstoichiometric oxides as a continuous homologous series: linear free-energy relationship in oxygen exchange
Author:
Affiliation:
1. Institute of Solid State Chemistry and Mechanochemistry
2. SB RAS
3. Novosibirsk
4. Russia
5. Novosibirsk State University
Abstract
A novel methodology based on the continuous homologous series is suggested for the analysis of oxygen exchange in practically important non-stoichiometric oxides. Linear free-energy relationship is established analogous to Brønsted equation or Taffel plot.
Funder
Russian Science Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2018/CP/C8CP02924E
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