High photocatalytic yield in the non-oxidative coupling of methane using a Pd–TiO2 nanomembrane gas flow-through reactor

Author:

Longo Victor1,De Pasquale Luana1,Tavella Francesco1,Barawi Mariam2ORCID,Gomez-Mendoza Miguel2,de la Peña O’Shea Víctor2ORCID,Ampelli Claudio1ORCID,Perathoner Siglinda1ORCID,Centi Gabriele1ORCID,Genovese Chiara1ORCID

Affiliation:

1. Department of Chemical, Biological, Pharmaceutical and Environmental Sciences and CASPE (INSTM), University of Messina, Viale F. Stagno D’Alcontres 31, 98166 Messina, Italy

2. Photoactivated Processes Unit, IMDEA Energy, Avda. Ramón de la Sagra, 3, Móstoles, 28935 Madrid, Spain

Abstract

Ultrafine Pd nanoclusters were deposited on TiO2 to achieve high efficiency in gas flow-through non-oxidative photo-catalytic methane coupling.

Funder

Ministerio de Ciencia e Innovación

H2020 European Research Council

Ministero dell'Università e della Ricerca

Publisher

Royal Society of Chemistry (RSC)

Reference81 articles.

1. Strategies for the Direct Catalytic Valorization of Methane Using Heterogeneous Catalysis: Challenges and Opportunities

2. CEFIC , Natural Gas: A Vital Energy And Feedstock Source For The Chemical Industry To Transition Towards A Competitive , Climate-Neutral , 2050 , https://cefic.org/media-corner/newsroom/natural-gas-a-vital-energy-and-feedstock-source-for-the-chemical-industry-to-transition-towards-a-competitive-climate-neutral-2050/ , (accessed 03/05/2024)

3. Direct Conversion of Methane to Value-Added Chemicals over Heterogeneous Catalysts: Challenges and Prospects

4. Selective Photocatalytic Oxidative Coupling of Methane via Regulating Methyl Intermediates over Metal/ZnO Nanoparticles

5. Catalysis for Selected C1 Chemistry

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