1,1-Olefin-bridged bis-(2-indenyl) metallocenes of titanium and zirconium-Reference-Cited by-同舟云学术

1,1-Olefin-bridged bis-(2-indenyl) metallocenes of titanium and zirconium

Published:2014 Issue:35 Volume:43 Page:13219-13231
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Morton Jason G. M.¹²³,Al-Shammari Haif⁴⁵,Sun Yunshan¹²³,Zhu Jiangtao¹²³,Stephan Douglas W.¹²³

Affiliation:

1. Department of Chemistry

2. University of Toronto

3. Toronto, Canada

4. Saudi Basic Industries Corporation

5. Riyadh 11551, Saudi Arabia

Abstract

Tetrasubstituted alkenes bearing geminal 2-indenyl substituents were synthesized and metallated to form a new class of ansa titanium and zirconium metallocene complexes containing a single sp²-hybridized carbon bridge.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT01583E

Reference46 articles.

1. M. P. McDaniel , Handbook of Transition Metal Polymerization Catalysts , Wiley , New Jersey , 2010

2. Ansa-metallocene polymerization catalysts: Effects of the bridges on the catalytic activities

3. Insights into group 4 and 5 ansa-bis(cyclopentadienyl) complexes with a single-atom bridge

4. ansa-Zirconocenes with Aluminum or Gallium in Bridging Positions

5. Zirconium Complexes Involving 2-Phosphorus-Substituted Indenyl Fragments

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