A bis(silylene)pyridine pincer ligand can stabilize mononuclear manganese(0) complexes: facile access to isolable analogues of the elusive d<sup>7</sup>-Mn(CO)<sub>5</sub> radical-Reference-Cited by-同舟云学术

A bis(silylene)pyridine pincer ligand can stabilize mononuclear manganese(0) complexes: facile access to isolable analogues of the elusive d⁷-Mn(CO)₅ radical

Published:2022 Issue:29 Volume:13 Page:8634-8641
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Kalra Shweta¹^ORCID,Pividori Daniel²,Fehn Dominik²^ORCID,Dai Chenshu³,Dong Shicheng³,Yao Shenglai¹,Zhu Jun³^ORCID,Meyer Karsten²^ORCID,Driess Matthias¹^ORCID

Affiliation:

1. Department of Chemistry: Metalorganics and Inorganic Materials, Technische Universität Berlin, Strasse des 17. Juni 135, Sekr. C2, D-10623 Berlin, Germany

2. Inorganic Chemistry, Department of Chemistry and Pharmacy, Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Egerlandstrasse 1, 91058 Erlangen, Germany

3. State Key Laboratory of Physical Chemistry of Solid Surface, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University, 361005 Xiamen, China

Abstract

An isolable bis(silylene)pyridine stabilized manganese(0) complex {κ3-[SiNSi]Mn(dmpe)}, isolobal to elusive Mn(CO)5 radical has been synthesized and fully characterised.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC03352F

Reference43 articles.

1. Synthetic Development and Chemical Reactivity of Transition-Metal Silylene Complexes

2. Electronic and steric properties of stable silylene ligands in metal(0) carbonyl complexes

3. New Vistas in N-Heterocyclic Silylene (NHSi) Transition-Metal Coordination Chemistry: Syntheses, Structures and Reactivity towards Activation of Small Molecules