Flavanthrone – a new ligand with accessible radical anion and dianion states: preparation of zwitterionic {(Cp2V)2(flavanthrone)} and {(Cp2V)2(chloranil)} complexes-Reference-Cited by-同舟云学术

Flavanthrone – a new ligand with accessible radical anion and dianion states: preparation of zwitterionic {(Cp2V)2(flavanthrone)} and {(Cp2V)2(chloranil)} complexes

Published:2020 Issue:26 Volume:44 Page:10849-10858
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Konarev Dmitri V.¹²³^ORCID,Andronov Mikhail G.¹²³⁴⁵,Batov Mikhail S.¹²³⁴⁵^ORCID,Kuzmin Alexey V.⁶²³,Khasanov Salavat S.⁶²³,Shestakov Alexander F.¹²³⁴⁵,Otsuka Akihiro⁷⁸⁹¹⁰¹¹^ORCID,Yamochi Hideki⁷⁸⁹¹⁰¹¹^ORCID,Kitagawa Hiroshi⁷⁸⁹¹⁰¹¹^ORCID,Lyubovskaya Rimma N.¹²³

Affiliation:

1. Institute of Problems of Chemical Physics RAS

2. Chernogolovka

3. Russia

4. Moscow State University

5. Leninskie Gory

6. Institute of Solid State Physics RAS

7. Division of Chemistry

8. Graduate School of Science

9. Kyoto University

10. Kyoto 606-8502

11. Japan

Abstract

Molecular structure, optical and magnetic properties of the radical anions and dianions of flavanthrone dye are presented. Flavanthrone and chloranil coordinate two vanadocenes forming zwitter-ionic {(Cp₂V⁺)₂(Flavanthrone²⁻)} and {(Cp₂V⁺)₂(QCl₄²⁻)}.

Funder

Kyoto University Education and Research Foundation

Accelerated Innovation Research Initiative Turning Top Science and Ideas into High-Impact Values

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/NJ/D0NJ01208D

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