B(C6F5)3: a robust catalyst for the activation of CO2 and dimethylamine borane for the N-formylation reactions-Reference-Cited by-同舟云学术

B(C6F5)3: a robust catalyst for the activation of CO2 and dimethylamine borane for the N-formylation reactions

Published:2018 Issue:19 Volume:42 Page:15847-15851
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Saptal Vitthal B.¹²³⁴⁵,Juneja Gaurav¹²³⁴⁵,Bhanage Bhalchandra M.¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Institute of Chemical Technology (Autonomous)

3. Matunga

4. Mumbai

5. India

Abstract

In this work, B(C₆F₅)₃ is utilized as an organocatalyst for the transition-metal-free N-formylation of amines using carbon dioxide (CO₂) as a C1 source and dimethylamine borane (Me₂NH·BH₃) as a green hydrogen transfer source at 80 °C.

Funder

University Grants Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/NJ/C8NJ02816H

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