Manganese-rich high entropy oxides for lithium-ion batteries:materials design approaches to address voltage fade

Author:

Huang Cynthia12ORCID,Luo Jessica13ORCID,Mansley Zachary R.4ORCID,Kingan Arun12,Rodriguez Campos Armando13ORCID,Wang Zhongling12ORCID,Marin Bernardez Edelmy J.13ORCID,Pace Alexis1,Ma Lu5,Ehrlich Steven N.5,Wang Lei14,Bock David C.14,Takeuchi Esther S.1234ORCID,Marschilok Amy C.1234ORCID,Zhu Yimei26ORCID,Yan Shan14ORCID,Takeuchi Kenneth J.1234ORCID

Affiliation:

1. Institute of Energy: Sustainability, Environment, and Equity, Stony Brook University, Stony Brook, New York, 11794, USA

2. Department of Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, New York 11794, USA

3. Department of Chemistry, Stony Brook University, Stony Brook, New York, 11794, USA

4. Interdisciplinary Science Department, Brookhaven National Laboratory, Upton, NY 11973, USA

5. National Synchrotron Light Source II, Brookhaven National Laboratory, Upton, NY 11973, USA

6. Department of Condensed Matter Physics and Materials Science, Brookhaven National Laboratory, Upton, New York 11973, USA

Abstract

Mn rich high entropy oxides were designed to improve voltage fade in Li-ion batteries. A mild co-precipitation method yielded a layered structure (HEO-L) with stacking faults and a spinel-layered hybrid structure (HEO-H) with cation mixing.

Funder

Basic Energy Sciences

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

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