Chemical and physical properties of low-molecular-weight poly(2,6-dimethyl-1,4-phenylene oxide) (LMW-PPO) synthesized by peroxydisulfate and metal/non-metal catalysts

Author:

Lu Yi-Fang1ORCID,Wu Song-Hai1,Wang Cong2,Liu Yong3,Huang Fu-Gen4,Song Bao-Dong1,Han Xu1ORCID

Affiliation:

1. Tianjin Key Laboratory of Chemical Process Safety and Equipment Technology, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, P.R. China

2. Heibei Key Laboratory of Hazardous Chemicals Safety and Control Technology, School of Chemical and Environmental Engineering, North China Institute of Science and Technology, Langfang 065201, Hebei, P.R. China

3. School of Chemistry and Chemical Engineering, Tianjin University of Technology, Tianjin 300384, P.R. China

4. Industrial Resources BU, Sinochem International Corporation, Beijing 100045, P.R. China

Abstract

Low-molecular-weight poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) can be obtained by peroxydisulfate and Cu(ii)/metal-free catalyst, and high-molecular-weight PPO can be mediated to shorter ones by peroxydisulfate.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

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