Remendable thermosetting polymers for isocyanate-free adhesives: a preliminary study

Author:

Dolci Elena12345,Michaud Guillaume678,Simon Frédéric678,Boutevin Bernard12345,Fouquay Stéphane9108,Caillol Sylvain12345

Affiliation:

1. Institut Charles Gerhardt

2. Montpellier

3. UMR CNRS 5253

4. Equipe Ingénierie et Architectures Macromoléculaires

5. Ecole Nationale Supérieure de Chimie de Montpellier

6. BOSTIK CRD

7. 60280 Venette

8. France

9. BOSTIK S.A. 16-32

10. 92902 Paris La Défense

Abstract

Based on a model study, a new bis-cyclic monomer bearing a Diels–Alder adduct was synthesized. This monomer was polymerized with a diamine to yield a thermoresponsive polyhydroxyurethane (PHU). This PHU is remendable at around 100 °C by retro Diels–Alder reaction.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

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