Diastereomeric dinickel(<scp>ii</scp>) complexes with non-innocent bis(octaazamacrocyclic) ligands: isomerization, spectroelectrochemistry, DFT calculations and use in catalytic oxidation of cyclohexane-Reference-Cited by-同舟云学术

Diastereomeric dinickel(ii) complexes with non-innocent bis(octaazamacrocyclic) ligands: isomerization, spectroelectrochemistry, DFT calculations and use in catalytic oxidation of cyclohexane

Published:2022 Issue:13 Volume:51 Page:5151-5167
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Dobrov Anatolie¹²,Darvasiová Denisa³,Zalibera Michal³^ORCID,Bučinský Lukáš³^ORCID,Jelemenská Ingrid³⁴,Rapta Peter³^ORCID,Shova Sergiu⁵,Dumitrescu Dan G.⁶^ORCID,Andrade Marta A.⁷^ORCID,Martins Luísa M. D. R. S.⁷^ORCID,Pombeiro Armando J. L.⁷⁸^ORCID,Arion Vladimir B.¹^ORCID

Affiliation:

1. University of Vienna, Institute of Inorganic Chemistry, Währinger Strasse 42, A-1090 Vienna, Austria

2. Universität Wien, Fakultät für Chemie, Institut für Biophysikalische Chemie, 1090 Wien, Austria

3. Institute of Physical Chemistry and Chemical Physics, Faculty of Chemical and Food Technology, Slovak University of Technology in Bratislava, Radlinského 9, SK-81237 Bratislava, Slovak Republic

4. Department of Chemistry, Faculty of Natural Sciences, Constantine the Philosopher University in Nitra, 949 74 Nitra, Slovak Republic

5. Inorganic Polymers Department, “Petru Poni” Institute of Macromolecular Chemistry, Aleea Gr. Ghica Voda 41 A, Iasi 700487, Romania

6. Elettra – Sincrotrone Trieste S.C.p.A., Strada Statale 14 – km 163, 5 in AREA Science Park 34149 Basovizza, Trieste, Italy

7. Centro de Química Estrutural, Institute of Molecular Sciences, Universidade de Lisboa, Av. Rovisco Pais, 1049-001 Lisboa, Portugal

8. Peoples’ Friendship University of Russia (RUDN University), Research Institute of Chemistry, 6 Miklukho-Maklaya Street, Moscow 117198, Russian Federation

Abstract

Dinickel(ii) complexes with non-innocent bis(octaazamacrocyclic) ligands were isolated as R,S/S,R and R,R/S,S-enantiomers.

Funder

Austrian Science Fund

Österreichische Agentur für Internationale Mobilität und Kooperation in Bildung, Wissenschaft und Forschung

Vedecká Grantová Agentúra MŠVVaŠ SR a SAV

Agentúra na Podporu Výskumu a Vývoja

Fundação para a Ciência e a Tecnologia

RUDN University

European Regional Development Fund

Publisher

Royal Society of Chemistry (RSC)