Ruthenium(ii) complexes with phosphonate-substituted phenanthroline ligands: synthesis, characterization and use in organic photocatalysis

Author:

Morozkov Gleb V.1ORCID,Abel Anton S.1ORCID,Filatov Mikhail A.2ORCID,Nefedov Sergei E.3ORCID,Roznyatovsky Vitaly A.1ORCID,Cheprakov Andrey V.1ORCID,Mitrofanov Alexander Yu.14ORCID,Ziankou Ilia S.14ORCID,Averin Alexei D.1ORCID,Beletskaya Irina P.1ORCID,Michalak Julien4,Bucher Christophe5,Bonneviot Laurent5ORCID,Bessmertnykh-Lemeune Alla45ORCID

Affiliation:

1. Lomonosov Moscow State University, Department of Chemistry, 1-3, Leninskie Gory, Moscow, 119991, Russia

2. School of Chemical and Pharmaceutical Sciences, Technological University Dublin, City Campus, Grangegorman, Dublin 7, Ireland

3. N.S. Kurnakov Institute of General and Inorganic Chemistry RAS, 119991, Leninsky pr., 31, Moscow, Russian Federation

4. Institut de Chimie Moléculaire de l'Université de Bourgogne, UMR CNRS 6302, Université Bourgogne Franche-Comté, 9 Avenue Alain Savary, 21078 Dijon, France

5. ENS de Lyon, UMR 5182, CNRS, Laboratoire de Chimie, 69342 Lyon, France

Abstract

[Ru(phen)(bpy)2]2+-type complexes with a P(O)(OEt)2-substituted phen ligand are efficient photocatalysts for photoreactions proceeding via the electron transfer and energy transfer pathways.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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