An acid/base switchable and reversibly cross-linkable polyrotaxane

Author:

Li Shijun1234,Weng Guan-Huan1234,Lin Wei1234,Sun Zhi-Bin1234,Zhou Mi567,Zhu Bin1234,Ye Yang1234,Wu Jing1234

Affiliation:

1. College of Material

2. Chemistry and Chemical Engineering

3. Hangzhou Normal University

4. Hangzhou 310036, P. R. China

5. College of Chemical Engineering and Materials

6. Zhejiang University of Technology

7. Hangzhou 310014, P. R. China

Abstract

A main chain-type polyrotaxane was fabricated based on the DP24C8/dialkylammonium recognition motif, in which the host could be controllably shuttled on the axle of the polyrotaxane upon acid–base stimuli and reversibly cross-linked via Pd coordination and decoordination.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

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