Sub-3 nm Rh nanoclusters confined within a metal–organic framework for enhanced hydrogen generation

Author:

Zhang Hui12345ORCID,Huang Maolin12345,Wen Jie12345,Li Yanping12345ORCID,Li Airong12345,Zhang Lianhong12345,Ali Arshid Mahmood6789,Li Yadong1011125

Affiliation:

1. The Center of New Energy Materials and Technology

2. College of Chemistry and Chemical Engineering

3. Southwest Petroleum University

4. Chengdu 610500

5. China

6. Department of Chemical & Materials Engineering

7. King Abdulaziz University

8. Jeddah 72523

9. Kingdom of Saudi Arabia

10. Department of Chemistry

11. Tsinghua University

12. Beijing 100084

Abstract

Rh@UIO-66, prepared by using the double-solvent host–guest strategy and excess reduction methods, exhibited a higher catalytic activity in AB hydrolysis compared with Rh/UIO-66 because the ultrafine Rh nanoparticles were confined to UIO-66 channels. This confinement effect played a key role in enhancing the catalytic activity for AB hydrolysis.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3