A strong hydride donating, acid stable and reusable 1,4-dihydropyridine for selective aldimine and aldehyde reductions-Reference-Cited by-同舟云学术

A strong hydride donating, acid stable and reusable 1,4-dihydropyridine for selective aldimine and aldehyde reductions

Published:2022 Issue:8 Volume:20 Page:1671-1679
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Hirao Yasukazu¹^ORCID,Eto Hajime¹,Teraoka Mitsuru¹,Kubo Takashi¹²^ORCID

Affiliation:

1. Department of Chemistry, Graduate School of Science, Osaka University, 1-1 Machikaneyama, Toyonaka, Osaka 560-0043, Japan

2. Innovative Catalysis Science Division (ICS), Institute for Open and Transdisciplinary Research Initiatives (OTRI), Osaka University, Suita, Osaka 565-0871, Japan

Abstract

A new sterically protected 1,4-dihydropyridine is a stable and regeneratable hydride donor in Brønsted and Lewis acid catalyzed reductions of aldimines and aldehydes.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/OB/D1OB02358F

Reference56 articles.

1. Towards a Comprehensive Hydride Donor Ability Scale

2. Thermodynamic and kinetic hydricities of metal-free hydrides

3. Recent advances in the chemistry of dihydropyridines

4. Asymmetric organocatalytic reductions mediated by dihydropyridines

5. Recent Developments in Asymmetric Transfer Hydrogenation with Hantzsch Esters: A Biomimetic Approach

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