[Au(Np<sup>#</sup>)Cl]: highly reactive and broadly applicable Au(<scp>i</scp>)–NHC catalysts for alkyne π-activation reactions-Reference-Cited by-同舟云学术

[Au(Np^#)Cl]: highly reactive and broadly applicable Au(i)–NHC catalysts for alkyne π-activation reactions

Published:2023 Issue:17 Volume:13 Page:5131-5139
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Rahman Md. Mahbubur¹,Gao Pengcheng¹,Zhao Qun¹²,Lalancette Roger¹,Szostak Roman³^ORCID,Szostak Michal¹^ORCID

Affiliation:

1. Department of Chemistry, Rutgers University, 73 Warren Street, Newark, NJ 07102, USA

2. State Key Laboratory of Biocatalysis and Enzyme Engineering, School of Life Sciences, Hubei University, Wuhan, China

3. Department of Chemistry, Wroclaw University, F. Joliot-Curie 14, Wroclaw 50-383, Poland

Abstract

We report [Au(NHC)Cl] complexes featuring IPr# ligands that hinge upon modular peralkylation of aniline. Wingtip-flexible [Au(Np#)Cl] is a broadly applicable catalyst with the reactivity outperforming [Au(IPr)Cl] and [Au(IPr*)Cl] complexes.

Funder

Rutgers, The State University of New Jersey

National Science Foundation

American Chemical Society Petroleum Research Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CY/D3CY00717K

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