Halogen-bond driven self-assembly of perfluorocarbon monolayers on silicon nitride

Author:

Abate Antonio12345,Dehmel Raphael1234,Sepe Alessandro12346,Nguyen Ngoc Linh789104,Roose Bart1234,Marzari Nicola789104,Hong Jun Ki11121314ORCID,Hook James M.1511161714ORCID,Steiner Ullrich1234ORCID,Neto Chiara11121314ORCID

Affiliation:

1. Adolphe Merkle Institute

2. University of Fribourg

3. CH-1700 Fribourg

4. Switzerland

5. Helmholtz-Zentrum Berlin für Materialien und Energie

6. Big Data Science Center

7. Theory and Simulations of Materials (THEOS)

8. National Centre for Computational Design and Discovery of Novel Materials (MARVEL)

9. École Polytechnique Fédérale de Lausanne

10. 1015 Lausanne

11. School of Chemistry

12. University of Sydney Nano Institute

13. The University of Sydney

14. Australia

15. Mark Wainwright Analytical Centre

16. University of New South Wales

17. Sydney

Abstract

We demonstrate that self-assembled monolayers of reproducible thickness can be formed on silicon nitride, driven by halogen bonding using iodo-perfluorinated molecules.

Funder

Adolphe Merkle Foundation

University of Sydney

Seventh Framework Programme

Australian Research Council

Engineering and Physical Sciences Research Council

National Center of Competence in Research Materials' Revolution: Computational Design and Discovery of Novel Materials

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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