Influence of framework Si/Al ratio and topology on electron transfers in zeolites

Author:

Crémoux T.1234,Batonneau-Gener I.5674,Moissette A.1234ORCID,Paillaud J.-L.8910114ORCID,Hureau M.1234,Ligner E.8910114,Morais C.5674,Laforge S.5674,Marichal C.8910114,Nouali H.8910114

Affiliation:

1. LASIR

2. Université de Lille

3. Villeneuve d’Ascq 59655

4. France

5. IC2MP

6. Université de Poitiers

7. Poitiers 86073

8. Université de Haute Alsace

9. CNRS

10. IS2M UMR 7361

11. F-68100 Mulhouse

Abstract

From experimental results on H-ZSM-5 and H-*BEA zeolites, it is shown that the stability of radical cations and of charge transfer complexes (CTC) is highly dependent on the distance between Brønsted sites and strong Lewis sites or Brønsted Strong Lewis Pairs (BSLPs).

Funder

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference42 articles.

1. A. Moissette , M.Hureau , H.Vezin and R. F.Lobo , in Electron transfers under confinement in channel type zeolites , ed. A. Douhal and M. Anpo , Eslevier , Waltham, MA , 2019 , in press

2. Chemical Control of Photoinduced Charges under Confinement in Zeolites

3. Generation and Reactions of Organic Radical Cations in Zeolites

4. Encapsulated Conducting Polymers

5. A Link between Reactivity and Local Structure in Acid Catalysis on Zeolites

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