A general mechanistic map of organocatalytic hydroboration of alkynes: polarity controlled switchable selective pathways-Reference-Cited by-同舟云学术

A general mechanistic map of organocatalytic hydroboration of alkynes: polarity controlled switchable selective pathways

Published:2024 Issue:14 Volume:11 Page:3952-3961
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Liu Chunhui¹,Han Peilin¹,Hou Xiaoxiao²,Ge Suxiang¹,Wei Donghui²^ORCID

Affiliation:

1. Key Laboratory of Micro-Nano Materials for Energy Storage and Conversion of Henan Province, Institute of Surface Micro and Nano Materials, College of Chemical and Materials Engineering, Xuchang University, Xuchang, Henan Province, 461000, P. R. China

2. College of Chemistry, Zhengzhou University, Zhengzhou, Henan Province, 450001, P. R. China

Abstract

A general mechanistic map for phosphine-catalyzed hydroboration of alkyne with HBpin involving multiple intermediates and competing pathways has been systematically studied by using density functional theory.

Funder

National Natural Science Foundation of China

Xuchang University

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/QO/D4QO00702F

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