Microstructural study of epoxy-based thermosets prepared by “classical” and cationic frontal polymerization

Author:

Švajdlenková Helena12345ORCID,Kleinová Angela1234ORCID,Šauša Ondrej6784ORCID,Rusnák Jaroslav9784ORCID,Dung Tran Anh5101112ORCID,Koch Thomas13101112,Knaack Patrick5101112

Affiliation:

1. Department of Synthesis and Characterization of Polymers

2. Polymer Institute of SAS

3. Bratislava 845 41

4. Slovakia

5. Institute of Applied Synthetic Chemistry

6. Department of Nuclear Physics

7. Institute of Physics of SAS

8. Bratislava 845 11

9. Department of Metal Physics

10. TU Wien

11. 1060 Vienna

12. Austria

13. Institute of Materials Science and Technology

Abstract

Epoxides prepared by cationic frontal polymerization have a greater reduced void fraction than “classically” cured samples revealing free-volume consequences of waves.

Funder

Vedecká Grantová Agentúra MŠVVaŠ SR a SAV

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference31 articles.

1. Polyesters from Epoxides and Anhydrides

2. H. Q.Pham and M. J.Marks , Chapter: Epoxy Resins , Ullmann's Encyclopedia of Industrial Chemistry , Wiley-VCH Verlag GmbH & Co. KGaA , Weinheim , 7th edn, 2012 , pp. 156–238

3. Metal-Catalyzed Transesterification for Healing and Assembling of Thermosets

4. J. A.Pojman , Frontal Polymerization: A Comprehensive Reference , ed. K. Matyjaszewski and M. Möller , Elsevier , Amsterdam , 2012 , pp. 957–980

5. UV-ignited frontal polymerization of an epoxy resin

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