Dicopper(ii) paddle-wheel metal–organic frameworks for high propyne storage under ambient conditions

Author:

Fu Xing-Ping12,Shen Ji-Wei1,Chen Ling1,Zhong De-Xin1,Wang Yu-Ling1ORCID,Liu Qing-Yan1ORCID

Affiliation:

1. College of Chemistry and Chemical Engineering, Key Lab of Fluorine and Silicon for Energy Materials and Chemistry of Ministry of Education, Jiangxi Normal University, Nanchang 330022, Jiangxi, P. R. China

2. Department of Ecological and Resources Engineering, Fujian Key Laboratory of Eco-industrial Green Technology, Wuyi University, Wuyishan 354300, Fujian, P. R. China

Abstract

Dicopper(ii) metal–organic frameworks constructed from fluorinated ligands exhibit ultra-high propyne storage under ambient conditions, which results from the suitable pore space and strong propyne⋯propyne interactions.

Funder

National Natural Science Foundation of China

Ministry of Education of the People's Republic of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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