Molten state synthesis of nickel phosphides: mechanism and composition-activity correlation for electrochemical applications

Author:

Geva Rotem12ORCID,Levy Natasha Ronith3ORCID,Tzadikov Jonathan1,Cohen Reut4,Weitman Michal4,Xing Lidan5ORCID,Abisdris Liel1,Barrio Jesús1ORCID,Xia Jiawei1,Volokh Michael1ORCID,Ein-Eli Yair36ORCID,Shalom Menny1ORCID

Affiliation:

1. Department of Chemistry and Ilse Katz Institute for Nanoscale Science and Technology, Ben-Gurion University of the Negev, Beer-Sheva 8410501, Israel

2. Nuclear Research Center Negev, Beer-Sheva 84190, Israel

3. Department of Material Science and Engineering, Technion – Israel Institute of Technology, Haifa, 3200003, Israel

4. Department of Chemistry, Bar-Ilan University, Ramat-Gan 52900, Israel

5. School of Chemistry, South China Normal University, Guangzhou 510006, China

6. The Nancy and Stephen Grand Technion Energy Program, Technion – Israel Institute of Technology, Haifa, 3200003, Israel

Abstract

A straightforward, benign, scalable and low-cost molten-state synthesis of nickel phosphides with tunable phase composition, applied both as electrocatalysts for hydrogen evolution reaction and as anode materials for Li-ion batteries.

Funder

Planning and Budgeting Committee of the Council for Higher Education of Israel

Israel National Research Center for Electrochemical Propulsion

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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