Electrode instead of catalyst and enzyme. A greener protocol for the synthesis of new 2-hydroxyacetamide derivatives containing a γ-lactone ring-Reference-Cited by-同舟云学术

Electrode instead of catalyst and enzyme. A greener protocol for the synthesis of new 2-hydroxyacetamide derivatives containing a γ-lactone ring

Published:2016 Issue:3 Volume:18 Page:672-675
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Maleki Abbas¹²³⁴,Nematollahi Davood⁵⁶⁷⁴,Rasouli Fereshteh¹²³⁴,Zeinodini-Meimand Azam⁵⁶⁷⁴

Affiliation:

1. Department of Chemistry

2. Payame Noor University

3. Tehran

4. Iran

5. Faculty of Chemistry

6. Bu-Ali-Sina University

7. Hamedan 65174

Abstract

Electrochemical synthesis of novel 2-hydroxyacetamides was performed in a one-pot protocol including the oxygen activation, extradiol cleavage, lactonization and amide bond formation sequence without any catalyst and enzyme.

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/GC/C5GC01863C

Reference42 articles.

1. Dioxygenase enzymes: catalytic mechanisms and chemical models

2. A New Tripodal Iron(III) Monophenolate Complex: Effects of Ligand Basicity, Steric Hindrance, and Solvent on Regioselective Extradiol Cleavage

3. Evidence from Mechanistic Probes for Distinct Hydroperoxide Rearrangement Mechanisms in the Intradiol and Extradiol Catechol Dioxygenases

4. Extradiol Oxidative Cleavage of Catechols by Ferrous and Ferric Complexes of 1,4,7-Triazacyclononane: Insight into the Mechanism of the Extradiol Catechol Dioxygenases

5. Dioxygen Activation by Enzymes with Mononuclear Non-Heme Iron Active Sites

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