4,4′,5,5′-Tetraamino-3,3′-azo-bis-1,2,4-triazole and the electrosynthesis of high-performing insensitive energetic materials-Reference-Cited by-同舟云学术

4,4′,5,5′-Tetraamino-3,3′-azo-bis-1,2,4-triazole and the electrosynthesis of high-performing insensitive energetic materials

Published:2020 Issue:37 Volume:8 Page:19337-19347
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Yount Joseph R.¹²³⁴⁵^ORCID,Zeller Matthias⁶³⁴⁵,Byrd Edward F. C.⁷⁵,Piercey Davin G.¹²³⁴⁵^ORCID

Affiliation:

1. Department of Materials Engineering

2. Purdue Energetics Research Center

3. Purdue University

4. West Lafayette

5. USA

6. Department of Chemistry

7. Army Research Laboratory

Abstract

Electrochemical azo coupling of guanazine yields novel thermally insensitive high-explosive. DFT and EXPLO6.05 calculations reveal energetic properties that rival RDX making this a potentially cheap, and green alternative to traditional energetics.

Funder

Office of Naval Research

Graduate School, Purdue University

Army Research Office

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/TA/D0TA05360K

Reference71 articles.

1. An Energetic Triazolo-1,2,4-Triazine and its N-Oxide

2. Efficient Construction of Energetic Materials via Nonmetallic Catalytic Carbon–Carbon Cleavage/Oxime-Release-Coupling Reactions

3. Synthesis of AgN5 and its extended 3D energetic framework

4. Conjugated Energetic Salts Based on Fused Rings: Insensitive and Highly Dense Materials

5. 1,3-Bis(nitroimido)-1,2,3-triazolate Anion, theN-Nitroimide Moiety, and the Strategy of Alternating Positive and Negative Charges in the Design of Energetic Materials

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