Why one can expect large rectification in molecular junctions based on alkane monothiols and why rectification is so modest
Author:
Affiliation:
1. Department of Chemical Engineering and Materials Science
2. Department of Chemistry
3. University of Minnesota
4. Minneapolis
5. USA
6. Theoretische Chemie
7. Universität Heidelberg
8. D-69120 Heidelberg
9. Germany
Abstract
The Stark effect plays a key role in understanding why, against expectation, alkane thiols are not high-performance molecular rectifiers.
Funder
Deutsche Forschungsgemeinschaft
Division of Chemistry
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/SC/C8SC00938D
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