High-yield and sustainable synthesis of quinoidal compounds assisted by keto–enol tautomerism

Author:

Wang Cheng12345,Du Tian12345,Deng Yunfeng12345ORCID,Yao Jiarong26734,Li Riqing26734,Zhao Xuxia12345,Jiang Yu89105,Wei Haipeng89105ORCID,Dang Yanfeng26734ORCID,Li Rongjin26734ORCID,Geng Yanhou12345ORCID

Affiliation:

1. School of Materials Science and Engineering

2. Tianjin Key Laboratory of Molecular Optoelectronic Sciences

3. Tianjin University

4. Tianjin 300072

5. China

6. Department of Chemistry

7. School of Science

8. Joint School of National University of Singapore and Tianjin University

9. International Campus of Tianjin University

10. Fuzhou 350207

Abstract

Facilitated by the highly efficient Pd-catalyzed coupling and keto–enol-tautomerism-assisted spontaneous air oxidation, various indandione-terminated quinoidal compounds have been synthesized in isolated yields up to 95%.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Tianjin City

Ministry of Science and Technology of the People's Republic of China

Tianjin University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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