Palladium supported on magnesium hydroxyl fluoride: an effective acid catalyst for the hydrogenation of imines and N-heterocycles

Author:

Kokane Reshma12,Corre Yann34,Kemnitz Erhard5ORCID,Dongare Mohan K.6,Agbossou-Niedercorn Francine34ORCID,Michon Christophe347ORCID,Umbarkar Shubhangi B.12ORCID

Affiliation:

1. Catalysis Division, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune-411008, India

2. Academy of Scientific and Innovative Research, CSIR, Ghaziabad-201002, India

3. Univ. Lille, CNRS, Centrale Lille Institut, Univ. Artois, UCCS UMR 8181 – Unité de Catalyse et Chimie du Solide, F-59000 Lille, France

4. Centrale Lille, Bat C7, Cité Scientifique, CS20048, 59651 Villeneuve d'Ascq Cedex, France

5. Institute of Chemistry, Humboldt University, Brook-Taylor-Straße 2, 12489 Berlin, Germany

6. Malati Fine Chemicals Pvt. Ltd., Panchawati, Pune-411008, India

7. Université de Strasbourg, Université de Haute-Alsace, Ecole Européenne de Chimie, Polymères et Matériaux, CNRS, LIMA, UMR 7042, 25 rue Becquerel, 67087, Strasbourg, France

Abstract

Heterogeneous palladium catalysts were prepared for the effective hydrogenation of imines and N-heterocycles at low loadings without any acid additive.

Funder

Centre National de la Recherche Scientifique

Council of Scientific and Industrial Research, India

Ministère de l'Education Nationale, de l'Enseignement Superieur et de la Recherche

European Regional Development Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference104 articles.

1. P.Rylander , The Catalytic Hydrogenation in Organic Syntheses , Academic Press , London , 1979 , pp. 213–234

2. S.Nishimura , Handbook of Heterogeneous Catalytic Hydrogenations for Organic Synthesis , Wiley , New York , 2001 , pp. 497–571

3. J. G.De Vries and C. J.Elsevier , Handbook of Homogeneous Hydrogenation , Wiley-VCH , Weinheim, Germany , 2007

4. P. G.Andersson and I. J.Munslo , Modern Reduction Methods , Wiley-VCH , Weinheim , 2008

5. Asymmetric Catalysis by Architectural and Functional Molecular Engineering: Practical Chemo- and Stereoselective Hydrogenation of Ketones

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