The duality of UiO-67-Pt MOFs: connecting treatment conditions and encapsulated Pt species by operando XAS

Author:

Braglia L.12345ORCID,Borfecchia E.12345ORCID,Martini A.12345,Bugaev A. L.12345,Soldatov A. V.6789,Øien-Ødegaard S.101111213,Lønstad-Bleken B. T.101111213,Olsbye U.101111213ORCID,Lillerud K. P.101111213,Lomachenko K. A.678914ORCID,Agostini G.1415161718,Manzoli M.192021225ORCID,Lamberti C.67891ORCID

Affiliation:

1. Department of Chemistry

2. NIS Interdepartmental Centre and INSRM Reference Centre

3. University of Turin

4. I-10135 Turin

5. Italy

6. IRC “Smart Materials”

7. Southern Federal University

8. 344090 Rostov-on-Don

9. Russia

10. inGAP Centre for Research Based Innovation

11. University of Oslo

12. Oslo

13. Norway

14. European Synchrotron Radiation Facility (ESRF)

15. 38043 Grenoble Cedex 9

16. France

17. Leibniz Institute for Catalysis at the University of Rostock (LIKAT)

18. D-18059 Rostock

19. Department of Drug Science and Technology

20. NIS Interdepartmental Centre

21. University of Torino

22. 10125 Torino

Abstract

XAS study of Pt-functionalized UiO-67 MOFs shows that 2 types of catalytically active sites can be formed in MOF cavities isolated Pt-complexes and Pt nanoparticles.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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