Recognition of fractional non-innocent feature of osmium coordinated 2,2′-biimidazole or 2,2′-bis(4,5-dimethylimidazole) and their interactions with anions-Reference-Cited by-同舟云学术

Recognition of fractional non-innocent feature of osmium coordinated 2,2′-biimidazole or 2,2′-bis(4,5-dimethylimidazole) and their interactions with anions

Published:2015 Issue:29 Volume:44 Page:13204-13219
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Das Ankita¹²³⁴,Mobin Shaikh M.⁵⁶⁷⁸⁴,Lahiri Goutam Kumar¹²³⁴

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology Bombay

3. Mumbai 400076

4. India

5. Discipline of Chemistry

6. School of Basic Sciences

7. Indian Institute of Technology Indore

8. Indore 452017

Abstract

The non-innocent feature of osmium coordinated doubly deprotonated 2,2′-biimidazole derivatives in symmetric dimeric complexes leads to a mixed electronic structural configuration.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT01763G

Reference122 articles.

1. Preparation and electrochemistry of biimidazolate complexes of ruthenium(II)

2. Synthesis of mononuclear complexes of Ru and Os and heterobimetallic M–M′(M = Ru or Os; M′= Rh, Ir, or Au) compounds with pyrazolate or imidazolate type ligands. X-Ray crystal structure of [(Ph3P)2(OC)HRu(µ-bim)Rh(cod)](bim = dianion of 2,2′-bi-imidazole, cod = cyclo-octa-1,5-diene)

3. 1H NMR and electrospray mass spectrometry of the mono-ionized bis(2,2′-bis(4,5-dimethylimidazole)chloronitrosylruthenium(II) complex ([Ru(NO)Cl(LH2)2]+, LH2=2,2′-bis(4,5-dimethylimidazole)

4. Synthesis and electrochemical and photoemission properties of mononuclear and binuclear ruthenium(II) complexes containing 2,2'-bipyridine, 2,9-dimethyl-1,10-phenanthroline, 2,2'-bipyrimidine, 2,2'-biimidazole, and 2-pyridinecarboxaldimine ligands

5. Synthesis and protonation-deprotonation reactions of ruthenium(II) complexes containing 2, 2′-bibenzimidazole and related ligands

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