Synthesis of platinum nanoparticles on strontium titanate nanocuboids via surface organometallic grafting for the catalytic hydrogenolysis of plastic waste

Author:

McCullough Katherine E.1ORCID,Peczak Ian L.2,Kennedy Robert M.12ORCID,Wang Yi-Yu3,Lin James4,Wu Xun34ORCID,Paterson Alexander L.4,Perras Frédéric A.4ORCID,Hall Jacklyn1,Kropf A. Jeremy1ORCID,Hackler Ryan A.1,Shin Youngho5,Niklas Jens1ORCID,Poluektov Oleg G.1ORCID,Wen Jianguo6ORCID,Huang Wenyu34ORCID,Sadow Aaron D.34ORCID,Poeppelmeier Kenneth R.2,Delferro Massimiliano17ORCID,Ferrandon Magali S.1

Affiliation:

1. Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, USA

2. Department of Chemistry, Northwestern University, Evanston, Illinois 60208, USA

3. Department of Chemistry, Iowa State University, Ames, Iowa 50011, USA

4. U.S. DOE Ames National Laboratory, Ames, Iowa 50011, USA

5. Applied Materials Division, Argonne National Laboratory, Lemont, Illinois 60439, USA

6. Center for Nanoscale Materials, Argonne National Laboratory, Lemont, Illinois 60439, USA

7. Pritzker School of Molecular Engineering, University of Chicago, Chicago, Illinois 60637, USA

Abstract

Pt/SrTiO3 nanoparticle catalysts have been synthesized by surface organometallic chemistry in solution on a 5 g scale. Pt/SrTiO3 selectively and repeatedly upcycles isotactic polypropylene into uniform liquid products with Mn ∼ 200 Da.

Funder

U.S. Department of Energy

Office of Energy Efficiency and Renewable Energy

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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