Glycosylation with N-acetyl glycosamine donors using catalytic iron(iii) triflate: from microwave batch chemistry to a scalable continuous-flow process

Author:

Xolin Amandine1234,Stévenin Arnaud1234,Pucheault Mathieu567,Norsikian Stéphanie1234,Boyer François-Didier12348,Beau Jean-Marie12349

Affiliation:

1. Centre de Recherche de Gif

2. Institut de Chimie des Substances Naturelles

3. CNRS

4. F-91198 Gif-sur-Yvette, France

5. Institut des Sciences Moléculaires

6. UMR 5255 Bâtiment A11

7. F-33405 Talence, France

8. Institut Jean-Pierre Bourgin

9. Université Paris-Sud and CNRS

Abstract

Efficient glycosylation reactions of peracetylated β-d-N-acetyl glycosamines are described using catalytic iron(iii) triflate under microwave conditions or in a continuous flow process.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Reference69 articles.

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2. A. Varki , J. D.Esko , R. D.Cummings , H. H.Freeze , P.Stanley , C. R.Bertozzi , G. W.Hart and M. E.Etzler , Essentials of Glycobiology , Cold Spring Harbour Laboratory Press , Cold Spring Harbor, NY , 2nd edn, 2009

3. Oligosaccharide signalling for defence responses in plant

4. RHIZOBIUM LIPO-CHITOOLIGOSACCHARIDE NODULATION FACTORS: Signaling Molecules Mediating Recognition and Morphogenesis

5. Fungal lipochitooligosaccharide symbiotic signals in arbuscular mycorrhiza

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