Unravelling nucleophilic aromatic substitution pathways with bimetallic nucleophiles-Reference-Cited by-同舟云学术

Unravelling nucleophilic aromatic substitution pathways with bimetallic nucleophiles

Published:2019 Issue:12 Volume:55 Page:1805-1808
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Garçon Martí¹²³⁴^ORCID,Bakewell Clare¹²³⁴,White Andrew J. P.¹²³⁴,Crimmin Mark R.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Imperial College London

3. South Kensington

4. UK

Abstract

Reaction of nucleophiles containing polar (Fe–Mg) and apolar (Mg–Mg) bonds with 2-(pentafluorophenyl)pyridine are calculated to proceed by stepwise and concerted S_NAr pathways respectively.

Funder

Royal Society

Leverhulme Trust

H2020 European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C8CC09701A

Reference42 articles.

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