TiO<sub>2</sub> supported cobalt oxide for olefin epoxidation reaction – characterization, catalytic activities and mechanism – using a DFT model-Reference-Cited by-同舟云学术

TiO₂ supported cobalt oxide for olefin epoxidation reaction – characterization, catalytic activities and mechanism – using a DFT model

Published:2022 Issue:27 Volume:51 Page:10486-10500
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Mishra Subhashree¹^ORCID,Sangma Simon Watre¹^ORCID,Poddar Mukesh Kumar²,Bal Rajaram²³^ORCID,Singh G. P.⁴,Dey Ratan Kumar¹^ORCID

Affiliation:

1. Department of Chemistry, Central University of Jharkhand (CUJ), Ranchi – 835 205, India

2. Light and Stock Processing Division, CSIR-Indian Institute of Petroleum (IIP), Dehradun-248005, India

3. Academy of Scientific and Innovative Research (AcSIR), Ghaziabad-201002, India

4. Department of Nanoscience & Technology, Central University of Jharkhand (CUJ), Ranchi – 835 205, India

Abstract

Conversion of olefin to epoxide: Surface acidic sites of the catalysts allow the electron rich olefin to get adsorb on the catalyst and facilitate the bond cleavage to form epoxides.

Funder

Central University of Jharkhand

Indian Institute Of Petroleum, Council of Scientific and Industrial Research, India

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT01118B

Reference48 articles.

1. Aerobic Oxidations of Light Alkanes over Solid Metal Oxide Catalysts

2. Enhanced Metal–Support Interaction in Ni/Co3O4/TiO2 Nanorods toward Stable and Dynamic Hydrogen Production from Phenol Steam Reforming

3. Dry reforming of methane over Pt-Ni/CeO2 catalysts: Effect of the metal composition on the stability

4. Production of hydrogen by partial oxidation of methanol over bimetallic Au–Cu/TiO2–Fe2O3 catalysts

5. Dispersion and electronic structure of titania-supported cobalt and cobalt oxide

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