Turn-on type sensing of methanol vapor by a luminescent platinum(ii) dichloride complex with 21-dibenzoarsacrown-7

Author:

Sumida Akifumi1234,Imoto Hiroaki12345,Naka Kensuke12345ORCID

Affiliation:

1. Faculty of Molecular Chemistry and Engineering

2. Kyoto Institute of Technology

3. Kyoto 606-8585

4. Japan

5. Materials Innovation Lab

Abstract

Platinum(II) dichloride complex with 21-dibenzoarsacrown-7 can capture methanol vapor into the crystal matrix to turn on the luminescence. The present sensing system has high selectivity, rapid response time, and good reusability.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference37 articles.

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3. Mechanistic Pathways in the Catalytic Carbonylation of Methanol by Rhodium and Iridium Complexes

4. H. Cheung , R. S.Tanke and G. P.Torrence , in Ullmann's Encycl. Ind. Chem , Wiley-VCH Verlag GmbH & Co. KGaA , 2000

5. The use of pure methanol as fuel at high compression ratio in a single cylinder gasoline engine

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