Structural elucidation of a methylenation reagent of esters: synthesis and reactivity of a dinuclear titanium(iii) methylene complex-Reference-Cited by-同舟云学术

Structural elucidation of a methylenation reagent of esters: synthesis and reactivity of a dinuclear titanium(iii) methylene complex

Published:2021 Issue:10 Volume:12 Page:3509-3515
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Kurogi Takashi¹²³⁴⁵^ORCID,Kuroki Kaito¹²³⁴⁵^ORCID,Moritani Shunsuke¹²³⁴⁵^ORCID,Takai Kazuhiko¹²³⁴⁵^ORCID

Affiliation:

1. Division of Applied Chemistry

2. Graduate School of National Science and Technology

3. Okayama University

4. Okayama 700-8530

5. Japan

Abstract

Transmetallation of a zinc methylene complex [ZnI(tmeda)]₂(μ-CH₂) with a titanium(iii) chloride [TiCl₃(tmeda)(thf)] produced a titanium methylene complex.

Funder

Ministry of Education, Culture, Sports, Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D0SC06366E

Reference77 articles.

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