Trends in the valence band electronic structures of mixed uranium oxides

Author:

Kvashnina Kristina O.12345ORCID,Kowalski Piotr M.678910ORCID,Butorin Sergei M.1112131415ORCID,Leinders Gregory16171819ORCID,Pakarinen Janne16171819ORCID,Bès René20212223ORCID,Li Haijian678910,Verwerft Marc16171819ORCID

Affiliation:

1. Rossendorf Beamline at ESRF – The European Synchrotron

2. CS40220

3. 38043 Grenoble Cedex 9

4. France

5. Helmholtz Zentrum Dresden-Rossendorf (HZDR)

6. Institute of Energy and Climate Research

7. IEK-6

8. Nuclear Waste Management and Reactor Safety

9. Forschungszentrum Jülich GmbH

10. 52428 Jülich

11. Molecular and Condensed Matter Physics

12. Department of Physics and Astronomy

13. Uppsala University

14. SE-751 20 Uppsala

15. Sweden

16. Belgian Nuclear Research Centre (SCK·CEN)

17. Institute for Nuclear Materials Science

18. B-2400 Mol

19. Belgium

20. Department of Applied Physics

21. Aalto University

22. FI-00076 Aalto

23. Finland

Abstract

The valence band electronic structures of mixed uranium oxides (UO2, U4O9, U3O7, U3O8, and β-UO3) have been studied using the resonant inelastic X-ray scattering (RIXS) technique at the U M5 edge and computational methods.

Funder

Vetenskapsrådet

European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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