Photoactive ultrathin molecular nanosheets with reversible lanthanide binding terpyridine centers

Author:

Tang Zian1ORCID,Chulanova Elena12ORCID,Küllmer Maria1ORCID,Winter Andreas34ORCID,Picker Julian1ORCID,Neumann Christof1ORCID,Schreyer Kristin34,Herrmann-Westendorf Felix15,Arnlind Andreas1,Dietzek Benjamin145ORCID,Schubert Ulrich S.34ORCID,Turchanin Andrey14ORCID

Affiliation:

1. Institute of Physical Chemistry (IPC), Friedrich Schiller University Jena, Lessingstr. 10, 07743 Jena, Germany

2. Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090 Novosibirsk, Russia

3. Laboratory of Organic and Macromolecular Chemistry (IOMC), Friedrich Schiller University Jena, Humboldtstr. 10, 07743 Jena, Germany

4. Center for Energy and Environmental Chemistry Jena (CEEC Jena), Philosophenweg 7a, 07743 Jena, Germany

5. Leibniz Institute of Photonic Technology, Research Department Functional Interfaces, Albert-Einstein-Straße 9, 07745 Jena, Germany

Abstract

The synthesis of large scale and mechanically stable ∼1 nm thick molecular nanosheets showing reversible complexation of lanthanide ions is reported. Their tailored photoactive properties pave the way to novel devices concepts for energy conversion.

Funder

Deutsche Forschungsgemeinschaft

Deutscher Akademischer Austauschdienst

European Social Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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