Enhancing corannulene chemiluminescence, electrochemiluminescence and photoluminescence by means of an azabora-helicene to slow down its bowl inversion

Author:

Qin Xiaoli12ORCID,Huang Lin345ORCID,Zhan Ziying1,Fu Peng345,Wang Qing36,Zhang Congyang1,Huang Jianhui345ORCID,Ding Zhifeng1ORCID

Affiliation:

1. Department of Chemistry, Western University, London, ON N6A 5B7, Canada

2. College of Chemistry and Material Science, Hunan Agricultural University, Changsha 410128, China

3. School of Pharmaceutical Science and Technology, Faculty of Medicine, Tianjin University, Tianjin 300072, China

4. International Center of Chemical Science and Engineering, Tianjin 300072, China

5. International Joint Research Centre for Molecular Sciences, Tianjin University, Tianjin 300072, China

6. National Institute of Biological Sciences, No. 7 Science Park Road, Zhongguancun Life Science Park, Beijing 102206, China

Abstract

The enhancement of chemi-, electrochemi-, and photo-luminescence in a corannulene dialkyl borate has been successfully achieved for the first time through the incorporation of an azabora-helicene, slowing down the bowl inversion of the molecule.

Funder

Natural Sciences and Engineering Research Council of Canada

China Scholarship Council

National Natural Science Foundation of China

National Key Research and Development Program of China

Publisher

Royal Society of Chemistry (RSC)

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