More efficient spin–orbit coupling: adjusting the ligand field strength to the second metal ion in asymmetric binuclear platinum(ii) configurations-Reference-Cited by-同舟云学术

More efficient spin–orbit coupling: adjusting the ligand field strength to the second metal ion in asymmetric binuclear platinum(ii) configurations

Published:2020 Issue:25 Volume:49 Page:8722-8733
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Hao Zhaoran¹²³⁴⁵,Zhang Kai⁶⁷⁸⁹¹⁰,Chen Kuan¹¹¹¹²¹³¹⁴,Wang Pu¹²³⁴⁵,Lu Zhiyun¹¹¹¹²¹³¹⁴^ORCID,Zhu Weiguo⁶⁷⁸⁹¹⁰^ORCID,Liu Yu⁶⁷⁸⁹¹⁰^ORCID

Affiliation:

1. College of Chemistry

2. Key Lab of Environment-Friendly Chemistry and Application in Ministry of Education

3. Xiangtan University

4. Xiangtan 411105

5. China

6. School of Materials Science and Engineering

7. Jiangsu Collaboration Innovation Center of Photovoltaic Science and Engineering

8. Jiangsu Engineering Laboratory of Light-Electricity-Heat Energy-Converting Materials and Applications

9. National Experimental Demonstration Center for Materials Science and Engineering

10. Changzhou University

11. Key Laboratory of Green Chemistry and Technology of Ministry of Education

12. and State Key Laboratory of Polymer Materials Engineering

13. Sichuan University

14. Chengdu 610065

Abstract

Two types of asymmetric binuclear platinum(ii) complexes (Pt-1 and Pt-3) bearing different bridging ligands as well as their corresponding mononuclear counterparts (Pt-2, Pt-4, and Pt-5) were synthesized and characterized.

Funder

National Natural Science Foundation of China

Hunan Provincial Innovation Foundation for Postgraduate

State Key Laboratory of Luminescent Materials and Devices

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT00939C

Reference41 articles.

1. Highly Luminescent Dinuclear Platinum(II) Complexes Incorporating Bis-Cyclometallating Pyrazine-Based Ligands: A Versatile Approach to Efficient Red Phosphors

2. Dinuclear platinum(ii) complex dominated by a zig-zag-type cyclometalated ligand: a new approach to realize high-efficiency near infrared emission

3. Dinuclear Design of a Pt(II) Complex Affording Highly Efficient Red Emission: Photophysical Properties and Application in Solution-Processible OLEDs

4. Highly Luminescent Mixed-Metal Pt(II)/Ir(III) Complexes: Bis-Cyclometalation of 4,6-Diphenylpyrimidine As a Versatile Route to Rigid Multimetallic Assemblies

5. The luminescence properties of multinuclear platinum complexes

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