Conjugation-length dependence of regioregular oligo 3-alkyl(thienylene-vinylene)s demonstrates polyene-like behaviour with weak electron–electron correlations

Author:

Polak Daniel W.1ORCID,Andrews Iain2,Farrow George3,Musser Andrew J.4ORCID,Auty Alex3,Chekulaev Dimitri3,Weinstein Julia A.3ORCID,Heeney Martin2ORCID,Clark Jenny1ORCID

Affiliation:

1. Department of Physics and Astronomy, Hicks Building, Hounsfield Rd, Broomhall, Sheffield S3 7RH, UK

2. Department of Chemistry and Centre for Processable Electronics, Imperial College London, White City Campus, London, W12 0BZ, UK

3. Department of Chemistry, Dainton Building, The University of Sheffield, Brook Hill, Sheffield S3 7HF, UK

4. Department of Chemistry and Chemical Biology, 122 Baker Laboratory, Ithaca, New York 14853, USA

Abstract

A time-resolved spectroscopic study of 3-alkyl(thienylene-vinylene) oligomers which sheds light on their photophysical behaviour, assigning them to be a polyene-like system.

Funder

UK Research and Innovation

Engineering and Physical Sciences Research Council

University of Sheffield

Imperial College London

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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