An unknown component of a selective and mild oxidant: structure and oxidative ability of a double salt-type complex having κ1O-coordinated permanganate anions and three- and four-fold coordinated silver cations-Reference-Cited by-同舟云学术

An unknown component of a selective and mild oxidant: structure and oxidative ability of a double salt-type complex having κ1O-coordinated permanganate anions and three- and four-fold coordinated silver cations

Published:2019 Issue:49 Volume:9 Page:28387-28398
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Kovács Gréta Bettina¹²³⁴⁵,May Nóra V.¹²³⁴^ORCID,Bombicz Petra Alexandra¹²³⁴,Klébert Szilvia¹²³⁴,Németh Péter¹²³⁴,Menyhárd Alfréd⁶⁷³⁸,Novodárszki Gyula¹²³⁴^ORCID,Petrusevski Vladimir⁹¹⁰¹¹¹²,Franguelli Fernanda Paiva¹²³⁴,Magyari József¹³¹⁴¹⁵¹⁶,Béres Kende¹²³⁴,Szilágyi Imre Miklós⁵⁷³¹⁷,Kótai László¹²³⁴¹⁸^ORCID

Affiliation:

1. Research Centre for Natural Sciences

2. Hungarian Academy of Sciences

3. Budapest

4. H-1117 Hungary

5. Department of Inorganic and Analytical Chemistry

6. Department of Physical Chemistry and Materials Science

7. Budapest University of Technology and Economics

8. Hungary

9. Faculty of Natural Sciences and Mathematics

10. Ss. Cyril and Methodius University

11. Skopje

12. Republic of Macedonia

13. Department of Chemistry, Biochemistry and Environmental Protection

14. Faculty of Sciences, University of Novi Sad

15. Novi Sad

16. Serbia

17. H-1111 Hungary

18. Deuton-X Ltd.

Abstract

A compound having redox-active permanganate and complexed silver ions with reducing pyridine ligands is used as a mild organic and as a precursor for nanocatalyst synthesis in a low-temperature solid-phase quasi-intramolecular redox reaction.

Funder

Emberi Eroforrások Minisztériuma

Országos Tudományos Kutatási Alapprogramok

Magyar Tudományos Akadémia

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/RA/C9RA03230D

Reference68 articles.

1. Bispyridinesilver permanganate[Ag(C5H5N)2]MnO4: an efficient oxidizing reagent for organic substrates