Chiral phosphoric acid catalyzed atroposelective C–H amination of arenes: mechanisms, origin and influencing factors of enantioselectivity-Reference-Cited by-同舟云学术

Chiral phosphoric acid catalyzed atroposelective C–H amination of arenes: mechanisms, origin and influencing factors of enantioselectivity

Published:2021 Issue:1 Volume:8 Page:61-76
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Lu Ka¹²³⁴⁵,Liang Peng-Yu¹²³⁴⁵,Yan Chao-Xian¹²³⁴⁵,Yang Fang-Ling¹²³⁴⁵,Yang Xing¹²³⁴⁵,Dou Wei¹²³⁴⁵,Yu Qinwei⁶⁷⁸⁹,Yang Jianming⁶⁷⁸⁹,Zhou Pan-Pan¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory of Applied Organic Chemistry

2. Key Laboratory of Special Function Materials and Structure Design of Ministry of Education

3. Advanced Catalysis Center

4. College of Chemistry and Chemical Engineering

5. Lanzhou University

6. State Key Laboratory of Fluorine & Nitrogen Chemicals

7. Xi'an Modern Chemistry Research Institute

8. Xi'an

9. P. R. China

Abstract

The amination reaction between azonaphthalene and carbazole catalyzed by chiral phosphoric acid was theoretically investigated, and the mechanism, origin and influencing factors of enantioselectivity were elaborated.

Funder

Natural Science Foundation of Gansu Province

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/QO/D0QO01160F

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2. Occurrence, Biogenesis, and Synthesis of Biologically Active Carbazole Alkaloids